Well, are you using a sitz bath after you have your BM? That might help. So, if you do that, you'd put the Nitro on, maybe after you've let yourself dry a little from the sitz bath.
If you don't use the sitz, or any type of tub, you might want to wash your backside off in the shower, before applying the Nitro. --- BTW, I'm sure you know all of this - but it's essential to keep the area clean.
I usually use the Nitro throughout the day - less now than I did - but only on the end, 2-3 times per day. At one point I was using it more often, but I did develop headaches from it.
You might have to experiment a little with it.